Platinum(IV)-mediated coupling of dione monoximes and nitriles: A novel reactivity pattern of the classic oxime-based chelating ligands

Author(s)
Anastassiya V. Makarycheva-Mikhailova, M Haukka, Nadezhda A. Bokach, Dmitrii A. Garnovskii, Mathea Sophia Galanski, Bernhard Keppler, Armando J L Pombeiro, Vadim Yu Kukushkin
Abstract

The reaction between dione monoximes and platinum(IV) nitrile complexes leads, instead of the conventional substitution, to metal-mediated coupling, giving iminoacylated species which, on being liberated, undergo disintegration to the nitrile and the oxime.

Organisation(s)
Department of Inorganic Chemistry
External organisation(s)
Saint Petersburg State University, University of Joensuu, Peter the Great St.Petersburg Polytechnic University, Instituto Superior Técnico
Journal
New Journal of Chemistry
Volume
26
Pages
1085-1091
No. of pages
7
ISSN
1144-0546
Publication date
2002
Peer reviewed
Yes
Austrian Fields of Science 2012
1040 Chemistry
Portal url
https://ucrisportal.univie.ac.at/en/publications/007f9480-69a1-42f2-974e-cf51eb6181ee