Associated effects of storage and mechanical pre-treatments of microalgae biomass on biomethane yields in anaerobic digestion

Author(s)
M. R. Gruber-Brunhumer, J. Jerney, E. Zohar, M. Nussbaumer, C. Hieger, P. Bromberger, G. Bochmann, F. Jirsa, M. Schagerl, J. P. Obbard, W. Fuchs, B. Drosg
Abstract

The pre-treatment of microalgae cell walls is known to be a key factor to enhance methane (CH

4) yields during anaerobic digestion. This study investigated the combined effects of two different biomass storage methods and physical pre-treatments on the anaerobic digestion for three different microalgae species. Acutodesmus obliquus, Chlorella vulgaris and Chlorella emersonii were cultivated in 80 L sleevebag photobioreactors (batch mode), and then subjected to different storage (cooling and freezing) and pre-treatment methods prior to anaerobic digestion using the biochemical methane potential (BMP) test. A. obliquus was selected to evaluate pre-treatment methods for further experimentation. Significantly higher CH

4 yields of cooled (4 °C) A. obliquus biomass were achieved through ultrasonication (+53% CH

4) and wet-milling (+51% CH

4). These methods were then applied in follow-up experiments to cooled (4 °C) biomass of C. emersonii and A. obliquus. Ultrasonication again led to significantly higher CH

4 yields for A. obliquus biomass (323 dm

3 kg

−1 CH

4 yield calculated at standard gas conditions of 273 K, and 101.5 kPa per unit volatile solids, +41% CH

4), and C. emersonii biomass (308 dm

3 kg

−1; +35% CH

4). In a third experiment series, frozen A. obliquus and C. vulgaris biomass were thawed prior to pre-treatment and BMP-testing. Among all BMP tests, the highest CH

4 yields were achieved with untreated, freeze-thawed C. vulgaris biomass (406 dm

3 kg

−1); pre-treatment did not enhance CH

4 yields for C. vulgaris, but for A. obliquus (ultrasonication +20%). Pre-treatment was more effective for cooled than freeze-thawed microalgal biomass and combined effects acted strain dependently.

Organisation(s)
Department of Inorganic Chemistry, Functional and Evolutionary Ecology
External organisation(s)
University of Natural Resources and Life Sciences, BIOENERGY 2020+ GmbH, University of Helsinki, Erber Future Business GmbH, Fachhochschule Wiener Neustadt, University of Johannesburg (UJ), Qatar University
Journal
Biomass & Bioenergy
Volume
93
Pages
259-268
No. of pages
10
ISSN
0961-9534
DOI
https://doi.org/10.1016/j.biombioe.2016.07.013
Publication date
10-2016
Peer reviewed
Yes
Austrian Fields of Science 2012
104023 Environmental chemistry, 106020 Limnology, 106022 Microbiology
Keywords
ASJC Scopus subject areas
Forestry, Waste Management and Disposal, Agronomy and Crop Science, Renewable Energy, Sustainability and the Environment
Portal url
https://ucrisportal.univie.ac.at/en/publications/2127c2fa-4bd8-471f-8c0e-6d70637e13fa