A Canvas of Spatially Arranged DNA Strands that Can Produce 24-bit Color Depth

Author(s)
Tadija Kekic, Jory Lietard
Abstract

Nucleic acid microarray photolithography combines density, throughput, and positional control in DNA synthesis. These surface-bound sequence libraries are conventionally used in large-scale hybridization assays against fluorescently labeled, perfect-match DNA strands. Here, we introduce another layer of control for in situ microarray synthesis─hybridization affinity─to precisely modulate fluorescence intensity upon duplex formation. Using a combination of Cy3-, Cy5-, and fluorescein-labeled targets and an ensemble of truncated DNA probes, we organize 256 shades of red, green, and blue intensities that can be superimposed and merged. In so doing, hybridization alone is able to produce a large palette of 16 million colors or 24-bit color depth. Digital images can be reproduced with high fidelity at the micrometer scale by using a simple process that assigns sequence to any RGB value. Largely automated, this approach can be seen as miniaturized DNA-based painting.

Organisation(s)
Department of Inorganic Chemistry
Journal
Journal of the American Chemical Society
Volume
145
Pages
22293-22297
No. of pages
5
ISSN
0002-7863
DOI
https://doi.org/10.1021/jacs.3c06500
Publication date
10-2023
Peer reviewed
Yes
Austrian Fields of Science 2012
210002 Nanobiotechnology, 301303 Medical biochemistry
ASJC Scopus subject areas
Catalysis, General Chemistry, Biochemistry, Colloid and Surface Chemistry
Portal url
https://ucrisportal.univie.ac.at/en/publications/2a58f9b1-9d04-4c92-a69d-b0379e61db4d