Hydroxy and ether functionalized dithiolanes: Models for the active site of the [FeFe] hydrogenase
- Author(s)
- Ulf-Peter Apfel, Christian Kowol, Florian Kloss, Helmar Görls, Bernhard Keppler, Wolfgang Weigand
- Abstract
In attempt to synthesize suitable [FeFe] hydrogenase model complexes, 2-methoxypropane-1,3-dithiole and 4-methyl-4-hydroxy-1,2-dithiolane were reacted with Fe-3(CO)(12) to give the respective complexes [Fe-2(CO)(6)(H3COCH(CH2S)(2))] and [Fe-2(CO)(6)(HOC(CH3)(CH2S)(2))]. The compounds were characterized by H-1 and C-13 NMR spectroscopy, mass spectrometry and elemental analysis. In addition, their electrochemical properties were investigated by cyclic voltammetry and compared with that of [Fe-2(CO)(6)(HOC(CH2S)(2))] known from literature.
- Organisation(s)
- Department of Inorganic Chemistry
- External organisation(s)
- Friedrich-Schiller-Universität Jena
- Journal
- Journal of Organometallic Chemistry
- Volume
- 696
- Pages
- 1084-1088
- No. of pages
- 5
- ISSN
- 0022-328X
- DOI
- https://doi.org/10.1016/j.jorganchem.2010.09.048
- Publication date
- 2011
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 104003 Inorganic chemistry
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/2b620afe-383d-4646-8e1d-4654088689a9