Unprecedented twofold intramolecular hydroamination in diam(m)ine- dicarboxylatodichloridoplatinum(IV) complexes - ethane-1,2-diamine vs. ammine ligands
- Author(s)
- Michael Reithofer, Mathea Sophia Galanski, Vladimir Arion, Bernhard Keppler
- Abstract
Reaction of (OC-6-13)-bis(2Z-3-carboxyacrylato)dichlorido(ethane-1,2- diamine)platinum(iv) and (OC-6-13)-diamminebis(2Z-3-carboxyacrylato) dichloridoplatinum(iv) with propylamine in the presence of 1,1?-carbonyl diimidazole afforded not the expected amides; instead, beside amide formation, a twofold intramolecular attack of the am(m)ine ligand at the C=C bonds was observed involving either both (ethane-1,2-diamine) or only one (ammine) coordinated nitrogen atom(s).
- Organisation(s)
- Department of Inorganic Chemistry
- Journal
- Chemical Communications
- Pages
- 1091-1093
- No. of pages
- 3
- ISSN
- 1359-7345
- DOI
- https://doi.org/10.1039/b715680d
- Publication date
- 2008
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 104003 Inorganic chemistry
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/3e12d783-20ff-4ffb-a0ea-4fd5283c4447