Synthesis, characterisation and cytotoxicity of [(1,10-phenanthroline) (1R,2R,4R/1S, 2S,4S)-4-methyl-1,2-cyclohexanediamine) platinum(II)](2+) (PHEN-4-MeDACH)

Author(s)
K. Benjamin Garbutcheon-Singh, Mathea Sophia Galanski, Bernhard K. Keppler, Janice R. Aldrich-Wright
Abstract

We have synthesised, characterised and examined the cytotoxicity of [(1,10-phenanthroline)(1R,2R,4R/1S,2S,4S-4-methyl-cyclohexanediamine)platinum(II)]

2+ (PHEN-4-MeDACH) in the L1210 cell line. The cytotoxicity of PHEN-4-MeDACH in the murine leukaemia (L12010) cell line was 1.8 ± 0.00 μM, comparable with that of [(1,10-phenanthroline)(1R,2R-diaminocyclohexane)platinum(II)]

2+ (1.5 ± 0.14 μM) but less cytotoxic than [(1,10-phenanthroline)(1S,2S-diaminocyclohexane)platinum(II)]

2+ (0.10 ± 0.06 μM) and cisplatin (0.43 ± 0.06 μM).

Organisation(s)
NMR Centre, Department of Inorganic Chemistry
External organisation(s)
Western Sydney University
Journal
Inorganica Chimica Acta
Volume
441
Pages
152-156
No. of pages
5
ISSN
0020-1693
DOI
https://doi.org/10.1016/j.ica.2015.10.048
Publication date
02-2016
Peer reviewed
Yes
Austrian Fields of Science 2012
104003 Inorganic chemistry
Keywords
ASJC Scopus subject areas
Materials Chemistry, Inorganic Chemistry, Physical and Theoretical Chemistry
Portal url
https://ucrisportal.univie.ac.at/en/publications/42291421-7fc8-469b-be35-ab5be4906f52