Synthesis of fluorine-18-labeled ciprofloxacin for PET studies in humans

Author(s)
Oliver Langer, Markus Mitterhauser, Wolfgang Wadsak, Bernhard X Mayer, Kurt Kletter, Markus Müller
Abstract

Ciprofloxacin (1-cyclopropyl-6-fluoro-1,4-dihydro-4-oxo-7-(1-piperazinyl)- quinoline-3-carboxylic acid), a widely-prescribed antibiotic, was labeled with fluorine-18 with the aim to perform positron emission tomography studies in humans for pharmacokinetic measurements. Due to a lack of chemical activation of ciprofloxacin for a direct nucleophilic exchange reaction a novel two-step synthetic approach, which employed an activated 6-fluoro-7-chloro substituted precursor molecule, was developed. The radiosynthesis yielded, starting from 52.5 ‘ 11.3 GBq of [18F]fluoride, 1.3 ‘ 0.6 GBq (n = 13) [18F]ciprofloxacin ready for intravenous administration in about 130 min synthesis time. A series of analytical tests was performed in order to prove the identity of the radiolabeled compound and its suitability for human applications. Œ 2003 Elsevier Science Inc. All rights reserved.

Organisation(s)
Department of Inorganic Chemistry
External organisation(s)
Austrian Research Centers GmbH (ARC Seibersdorf), Medizinische Universität Wien
Journal
Nuclear Medicine and Biology
Volume
30
Pages
285-291
No. of pages
7
ISSN
0969-8051
Publication date
2003
Peer reviewed
Yes
Austrian Fields of Science 2012
3012 Pharmacy, Pharmacology, Toxicology
Portal url
https://ucrisportal.univie.ac.at/en/publications/55cb8e20-bd13-4b3e-9f3c-1b051f0c0768