Synthesis and structures of palladium(II) and platinum(II) complexes containing heterocyclic thiolate ligands formed by cycloaddition reactions of coordinated azides
- Author(s)
- Angela Fleischer, Alexander Roller, Vladimir Arion, Bernhard Keppler, Fabian Mohr
- Abstract
The phosphine-stabilized azido complexes [M(N3) 2(PTA)2] (M = Pd, Pt; PTA = 1,3,5-triaza-7- phosphaadamantane) were prepared in high yields by a ligand exchange reaction from cis-[Pd(N3)2(tmeda)] and cis-[Pt(N3) 2(cod)], respectively. The Pd and Pt complexes [M(N3) 2(PTA)2] undergo cycloaddition reactions with various isothiocyanates to give complexes containing anionic, S-coordinated tetrazole-thiolate ligands of the type trans-[M(SCN4R) 2(PTA)2] (M = Pd, Pt; R = Et, allyl, Me, Ph). The molecular structures of several of these derivatives were determined by X-ray crystallography.
- Organisation(s)
- Department of Inorganic Chemistry
- External organisation(s)
- Bergische Universität Wuppertal
- Journal
- Canadian Journal of Chemistry
- Volume
- 87
- Pages
- 146-150
- No. of pages
- 5
- ISSN
- 0008-4042
- DOI
- https://doi.org/10.1139/V08-115
- Publication date
- 2009
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 104003 Inorganic chemistry
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/73e67eda-9bae-4ac3-8efd-a0526f0a64ac