Enabling Methods to Elucidate the Effects of Metal-based Anticancer Agents

Author(s)
D. Kreutz, C. Gerner, S. M. Meier-Menches
Abstract

Next-generation metal-based pharmaceuticals are considered promising therapeutic agents, which may follow novel modes of action and engage with different targets compared to classical platinum(ii) anticancer agents. However, appropriate methods and assays are required to provide evidence of such unprecedented drug effects. Mass spectrometry (MS) has proved useful in probing the reactivity and selectivity of metal-based anticancer agents on a molecular level and recently also in the cellular context, especially with regard to the proteome. This chapter will discuss the design and use of competitive experiments to investigate activation pathways and binding preferences of metal-based anticancer agents by identifying reaction products via different MS setups. Moreover, cell-based approaches are described to obtain insights into novel potential targets and modes of action. Thus, mass spectrometry emerges as an enabling technology that connects molecules to mechanisms, highlighting the broad applicability of this analytical technique to the discovery and understanding of metal-based anticancer agents.

Organisation(s)
Department of Analytical Chemistry, Mass Spectrometry Centre
Pages
246-270
No. of pages
25
DOI
https://doi.org/10.1039/9781788016452-00246
Publication date
04-2019
Peer reviewed
Yes
Austrian Fields of Science 2012
104002 Analytical chemistry, 104003 Inorganic chemistry, 301904 Cancer research
ASJC Scopus subject areas
Biochemistry, Genetics and Molecular Biology (miscellaneous)
Sustainable Development Goals
SDG 3 - Good Health and Well-being
Portal url
https://ucrisportal.univie.ac.at/en/publications/988b3bd2-fb74-4397-b7ab-2b7d7bfab398