Tetrachloroferrate containing ionic liquids: Magnetic- and aggregation behavior

Author(s)
Daniel Kogelnig, Anja Stojanovic, Frank von der Kammer, Peter Terzieff, Mathea Sophia Galanski, Franz Jirsa, Regina Krachler, Thilo Hofmann, Bernhard Keppler
Abstract

The magnetic behavior of a binary salt of tricaprylylmethylammonium tetrachloroferrate and tricaprylylmethylammonium chloride, [A336][FeCl4](0.73)[Cl](0.27), was evaluated. With a magnetic susceptibility of 0.011 emu mol(-1) this binary salt exhibited a remarkable response to an external magnetic field. Dynamic light scattering (DLS) measurements allowed to study the aggregation behavior of [A336][FeCl4](0.73)[Cl](0.27) as well as of further magnetic ionic liquids [PR6,6,6,14][FeCl4] and (BMIM)[FeCl4] in ethylacetate and ethanol.

Organisation(s)
Department of Inorganic Chemistry, Department of Functional Materials and Catalysis
Journal
Inorganic Chemistry Communications
Volume
13
Pages
1485-1488
No. of pages
4
ISSN
1387-7003
DOI
https://doi.org/10.1016/j.inoche.2010.08.023
Publication date
2010
Peer reviewed
Yes
Austrian Fields of Science 2012
104003 Inorganic chemistry
Portal url
https://ucrisportal.univie.ac.at/en/publications/tetrachloroferrate-containing-ionic-liquids-magnetic-and-aggregation-behavior(a6fa29f3-87b6-41a0-b49d-fe07ebd54d0c).html