On the coordination properties of new bicyclophosphite-carbohydrates
- Author(s)
- Alexey Nazarov, Mikhail P. Koroteev, Christian Hartinger, Bernhard Keppler, Eduard E. Nifant'ev
- Abstract
The coordination behavior of newly developed bicyclophosphite ligands toward Mo(0), Rh(I), and Pt(II) was studied. Reactions at different ratios of metal to ligand were done. It was found that the ligands act as monodentate ones and form with hexacarbonylmolybdenum(0) complexes with the general formula Mo(CO)5L by replacing only one carbonyl ligand. Coordination experiments toward acetylacetonatodicarbonylrhodium(I) resulted in the formation of undefined compounds. Toward dichlorocyclooctadienylplatinum(II) the monomeric phosphorus ligands act as monodentate ligands forming complexes of the general structure cis-PtCl2L2. All the synthesized platinum-complexes possess cis-configuration (proven by 31P NMR). The corresponding coordination compounds were isolated and characterized by elemental analyses and 1H, 13C, and 31P NMR. ΠSpringer-Verlag 2004.
- Organisation(s)
- Department of Inorganic Chemistry
- External organisation(s)
- Moscow State Pedagogical University (MSPU)
- Journal
- Monatshefte für Chemie
- Volume
- 136
- Pages
- 137-146
- No. of pages
- 10
- ISSN
- 0026-9247
- Publication date
- 2005
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 1040 Chemistry
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/b517ddba-ca73-485d-a7fc-b171cf8a60e9