Optimization of [C-11]DASB-synthesis: Vessel-based and flow-through microreactor methods

Author(s)
Johanna Ungersböck, Cecile Philippe, Daniela Haeusler, Markus Mitterhauser, Rupert Lanzenberger, Robert Dudczak, Wolfgang Wadsak
Abstract

The intention for the present study was to implement a microfluidic set-up for N-C-11-methylations in a flow-through microreactor device with [C-11]DASB as model-compound and [C-11]CH3I and [C-11]CH3OTf, respectively, as C-11-methylation agents. Due to an observed "aging" effect of the C-11-methylation agents' solution, this goal was not achieved. Nevertheless, based on these observations, the time consumption for the vessel-based routine production of [C-11]DASB was reduced (34 +/- 1 min) and RCY was increased to 45.1 +/- 4.6% (EOB; 5.2 +/- 0.95 GBq EOS).

Organisation(s)
Department of Inorganic Chemistry
External organisation(s)
Medizinische Universität Wien
Journal
Applied Radiation and Isotopes
Volume
70
Pages
2615-2620
No. of pages
6
ISSN
0969-8043
DOI
https://doi.org/10.1016/j.apradiso.2012.08.001
Publication date
2012
Peer reviewed
Yes
Austrian Fields of Science 2012
302054 Nuclear medicine, 104003 Inorganic chemistry
Portal url
https://ucrisportal.univie.ac.at/en/publications/dfb634c2-a716-4d8d-92a3-f7ed6d1ac2aa